Iron and Steel An introduction to the metallurgy of by HM Boylston Hard Cover

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Iron and Steel An introduction to the metallurgy of by HM Boylston Hard Cover
 
Iron and Steel An introduction to the metallurgy of by HM Boylston
Copyright 1928   Staining  on several pages
Hard Cover
571 pages Indexed
CONTENTS
CHAPTER I
THE HISTORICAL AND ECONOMIC BACKGROUND OF THE IRON
AND STEEL INDUSTRY
ANTIQUITY OF IRON
EARLY MANUFACTURE OF IRON FROM THE ORE
THE CATALAN FORGE
EARLY STEEL PROCESSES
INVENTION OF THE BESSEMER STEELMAKING PROCESS
INVENTION OF THE SIEMENS GAS PRODUCER AND THE OPEN-HEARTH FURNACE
SORBY'S EARLY METALLOGRAPHIC WORK
DEVELOPMENT OF EARLY AMERICAN BLAST FURNACES
FIRST USE OF METALLURGICAL MICROSCOPE IN THE UNITED STATES .
ECONOMIC ASPECTS OF THE IRON AND STEEL INDUSTRY
GENERAL REFERENCES
CHAPTER II
CHEMICAL AND PHYSICAL PRINCIPLES
REDUCTION AND OXIDATION  25
CHEMICAL CONSTITUENTS 26
REDUCTION OF IRON ORE27
REDUCING AGENTS  28
SOURCE OF IMPURITIES IN IRON  28
EARLY PROCESSES FOR REDUCING IRON ORE  28
ABSORPTION OF CARBON BY IRON  30
OXIDATION REACTIONS -30
DEFINITIONS  30
CHAPTER III
THE RAW MATERIALS OF THE IRON INDUSTRY
IRON ORES    36
METHODS OF MINING AND HANDLING ORES 46
THE BENEFICIATION OF IRON ORES  51
BLAST-FURNACE FUELS  52
Manufacture of Charcoal  55
Manufacture of Coke 55
The Bee-hive Oven  57
The By-product Oven     60
LIMESTONE  67
AIR  69
GENERAL REFERENCES -76
CHAPTER IV
THE BLAST FURNACE AND THE MANUFACTURE OF PIG IRON
THE BLAST FURNACE 79
BLAST-FURNACE OPERATION 101
BLAST-FURNACE REACTIONS -109
GRADES OF PIG IRON AND THEIR USES 116
U. S. PRODUCTION OF PIG IRON, BY GRADES 118
CLASSIFICATION OF IRON ACCORDING TO USE 119
REMELTING IRONS -119
PUDDLING, FORGE, OR MILL IRON 120
STEELMAKING IRONS -120
FERRO-ALLOYS 123
DIRECT CASTINGS 124
TOTAL PRODUCTION OF PIG IRON125
CHEMICAL CHARACTERISTICS OF PIG IRON 125
GENERAL REFERENCES 127.
CHAPTER V
THE FOUNDRY
THE GRAY-IRON FOUNDRY 128
THE MELTING DEPARTMENT 137
MELTING FURNACES 138
The Cupola 138
The Air Furnace  149
THE MALLEABLE IRON INDUSTRY _ 150
Historical150
The Process of Manufacturing Malleable Cast Iron 151
Physical Properties of Malleable Cast Iron159
THE STEEL FOUNDRY 161
Specifications for Steel Castings...............174
Physical Properties of Steel Castings 176
The Heat Treatment of Steel Castings...179
Physical Properties of Heat-treated Steel Castings 179
Defects in Steel Castings180
CHAPTER VI
WROUGHT IRON
PAGE
HISTORICAL -186
THE DRY PUDDLING PROCESS 187
DEFINITION OF WROUGHT IRON  187
THE MODERN PUDDLING PROCESS  188
KNOBBLED CHARCOAL IRON  193
BUSIIELED IRON  194
MECHANICAL PUDDLING FURNACES  194
CHEMICAL COMPOSITION OF WROUGHT IRON  199
PHYSICAL PROPERTIES OF WROUGHT IRON  199
CHAPTER VII
EARLY STEEL-MARING PROCESSES
THE CEMENTATION PROCESS  205
THE CRUCIBLE PROCESS  207
CHAPTER VIII
THE BESSEMER PROCESS
HISTORICAL    213 THE PROCESS IN BRIEF     214
THE CONVERTER  215
CHEMISTRY OF THE ACID BESSEMER PROCESS  223
BASIC BESSEMER PROCESS  227
THE DEVELOPMENT OF THE BESSEMER-STEEL PROCESS  228
THE DEVELOPMENT OF THE OPEN-HEARTH PROCESS  229
CHAPTER IX
THE OPEN-HEARTH PROCESS
THE FURNACE     232 FUELS.. 235
ACID OPEN-HEARTH PROCESS  243
BASIC OPEN-HEARTH PROCESS  260
STATIONARY AND TILTING FURNACES  262
TILTING FURNACES 262
THE WELLMAN FURNACE  263
THE CAMPBELL FURNACE  263
THE CAMPBELL PROCESS  263
THE BERTRAND-THIEL PROCESS  263
THE TALBOT PROCESS 263
THE MONELL PROCESS  266
RECENT IMPROVEMENTS IN OPEN-HEARTH DESIGN 266
DUPLEX PROCESS FOR STEEL MAKINGrk 275
TRIPLEX PROCESS  276
REFRACTORIES FOR THE OPEN-HEARTH FURNACE  276
GENERAL REFERENCES ON THE OPEN-HEARTH PROCESS  278
CHAPTER X
THE ELECTRIC FURNACE PROCESS
HISTORICAL  279
ELECTRIC SMELTING FURNACES  281
ELECTRIC STEELMAKING PROCESSES 282
DISTRIBUTION OF ELECTRIC STEELMAKING FURNACES  282
ELECTRIC STEELMAKING FURNACES  283
SERIES-ARC FURNACES  286
Selected References to Articles on the Series-arc Furnaces 302
ELECTRODE-HEARTH FURNACES  302
Selected References to Articles on the Electrode-hearth Furnaces305
INDEPENDENT-ARC FURNACES 307
References to Articles on the Stassano Furnace  307
INDUCTION FURNACES  309
Selected References to Articles on Induction Furnaces   311
ELECTRIC STEEL-MELTING PROCESSES - 312
THE BASIC PROCESS  312
ACID PRACTICE  317
THE HOT-METAL BASIC PROCESS - 317
GENERAL REFERENCES  321
CHAPTER XI
THE MANUFACTURE OF COMMERCIALLY PURE IRON
A1,IERICAN INGOT IRON  322
The Development of Armco Ingot Iron  322
The Process of Making Ingot Iron  324
Physical Properties of Armco Ingot Iron   327
ELECTROLYTIC IRON  328
Physical Properties  333
CHAPTER XII
INGOTS AND INGOT MAKING
METHODS OF TEEMING 335
METHODS OF POURING 335
STRIPPING THE INGOT  343
SOAKING PITS  344
THE COOLING OF THE INGOT  347
PRINDEFECTS IN A STEEL INGOT  348
Pi g 348
Sound Ingots 352
Solidification of the Molten Steel in the Mold  352
Piping Steel  353
Open Steel  358
Blow-holes  358
Segregation  359
Ingotism  366
REFERENCES ON INGOTS AND INGOT MAKING  367
CHAPTER XIII
THE MECHANICAL TREATMENT OF STEEL
IMPORTANCE OF MECHANICAL TREATMENT  369
HOT WORK  370
Blooming Mills  371
Billet Mills  373
Reheating Furnaces  378
Finishing Mills  379
Bar Mills    380
Rod Mills 381
Slabbing Mills  385
Plate Mills  386
Manufacture of Rails  388
Structural Shapes  390
Sheet Rolling  391
Forging  393
Comparison of Rolling, Hammer-forging, and Pressing 395
Seamless Tubing 404
The Effect of Hot Work on the Structure and Physical Properties of Steel408
Importance of Finishing Temperature  409
COLD WORK 409
Cold-rolled Sheets  409
Cold-rolled Strip Steel  409
Cold Drawing of Wire  413
Effect of Cold Work on the Structure and Physical Properties of Steel416

CHAPTER XIV
THE COMPOSITION, STRUCTURE, AND PHYSICAL PROPERTIES OF
IRON AND STEEL
EARLY DEVELOPMENTS OF METALLOGRAPHY  424
THE CRITICAL POINTS IN IRON AND STEEL  424
MICROSTRUCTURE OF PURE IRON 432
FERRITE  434
PEARLITE  435
CEMENTITE, * 440
EFFECT OF CARBON CONTENT ON THE PHYSICAL PROPERTIES OF STEEL. 442
EFFECT OF CARBON ON THE SHOCK-RESISTING PROPERTIES 01' STEEL 443
IMPURITIES IN IRON AND STEEL  444
CARBON  445
SILICON  445
PHOSPHORUS  446
SULPHUR 447
MANGANESE  448
OXYGEN 452
NITROGEN.  454
HYDROGEN     454
NICKEL  455
CHROMIUM  460
NICKEL-CHROMIUM 463
VANADIUM  467
CHROME-VANADIUM  472
TUNGSTEN  475
HIGH-SPEED STEEL  478
MOLYBDENUM  485
COBALT  490
COPPER  491
CHAPTER XV
THE HEAT TREATMENT OF STEEL
ANNEALING  496
TOUGHENING TREATMENTS  523
HARDENING - 525
TEMPERING DRAWING)  531
CARBURIZING AND CASEHARDENING  541
APPENDIX
A. S. T. M. TENTATIVE DEFINITIONS OF TERMS RELATING TO HEAT TREATMENT OPERATIONS
INDEX



INTRODUCTION
IT is the author's firm conviction, that every engineer should have a basic knowledge of the metallurgy of iron and steel. Without the aid of these valuable metals civilization would indeed revert to the Stone Age. Not only the metal industry but all industries are dependent upon these metals for their existence.
A nation's industrial vitality is measured by its metal production, and the metal industry is often referred to as the pulse of American business. The production of pig iron alone is the basis for many business forecasts.
The metallurgy of iron and steel may be divided into three parts: process metallurgy, or the winning of the metal from its ores and the refining of the metal to a quality which will be of the best and most economical service to the industries that use it; mechanical metallurgy, or the processes of working steel, shaping it, and fabricating it into finished or semi-finished products; and the metallography and heat treatment of iron and steel, which deal with the properties of finished and semi-finished products and methods of improving them in order that they may be of the greatest possible service to industry.
The present treatise is an attempt to introduce all of these subjects to the reader in a concise form, and special emphasis has been placed upon the subject of ingots and ingot making, since a knowledge of this subject is necessary for an understanding of the difficulties encountered in the rolling-mill and heat-treatment departments. An endeavor has been made to bring up to date the subject of electric furnaces for the iron and steel industry and the

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